The use of personal protective equipment (PPE), particularly single-use surgical face masks (FMs), has increased drastically owing to the ongoing Covid-19 pandemic. This study aimed to demonstrate the feasibility of utilizing recycled FM fibers in cement mortar. For this, FMs were used by removing the inner nose wires and ear loops and cutting them into two different sizes: 10 mm × 5 mm and 20 mm × 5 mm. The FMs were then introduced into five mixtures at 0 (control), 0.10, 0.15, 0.20, and 0.25 % by volume. The following mechanical properties of the mixtures were then tested: workability, density, porosity, water absorption, and the related strengths (compressive, direct tensile, and flexural). In addition, the microstructures of the mixtures were analyzed using a scanning electron microscope. The results revealed that introducing FM fibers, particularly an FM with a 5 mm diameter and 10 mm length, in the mortar increased both the tensile and flexural strengths. Among the various combinations of FMs studied, a mixture containing 0.15 % FMs exhibited the best performance. The findings of this research reveal that FMs can be reused as fibers to enhance the tensile and flexural strengths of cement mortar.

Global public response to the COVID-19 (SARS-CoV-2) pandemic is highly focused on human health. However, conservationists have cautioned of unprecedented threats to the natural environment from a new type of non-biodegradable microplastic waste resulting from extensive use of disposable medical face masks (DMFMs). Thus, this waste must be recycled in an eco-friendly manner on an urgent basis. In this research, we developed a new environmentally friendly recycling technique using waste DMFMs in sustainable green concrete. More explicitly, a new fiber hybridization approach has been introduced in which two types of fibers namely DMFM fiber and basalt fiber (BF) were incorporated into fiber reinforced recycled aggregate concrete (FRAC). The volume fractions of DMFM fiber were 0%, 0.1%, and 0.2% and the volume fractions of BF were 0%, 0.25%, and 0.5%. In addition, two mineral admixtures (fly ash and ground granulated blast furnace slag) were also used. Test results indicated increase of approximately 12% in compressive strength, 26% in split tensile strength, and 60% in flexural strength of FRAC containing hybrid fibers and mineral admixtures. The density and ultra-sonic pulse velocity (UPV) of DMFM fiber- and BF-modified FRAC ranged from 2406-2433 kg/m and 4502-4541 m/s, respectively, which meets structural concrete requirements. The water absorption rate gradually increased with an increase in the volume fractions of fibers but remained within the allowable water absorption limit for construction materials. Lastly, the microstructure investigation indicated excellent concrete quality, improved interfacial transition zones (ITZs), and good compatibility of host concrete matrix with both DMFM fiber and BF that correlates well with the experimental results reported in this study.

Recently, COVID-19 has appeared as an international pandemic, leading to serious risks for humans. Using face masks is one of the most common measures in a wide-ranging prevention program that could control the COVID-19 dissemination. Face masks are typically composed of non-biodegradable and non-renewable polymers based on petroleum, which are harmful to nature and lead to health problems. In the present study, disposable face masks, the use of which has increased due to the Covid-19 pandemic throughout the world and which cause environmental pollution, were divided into very small pieces and utilized as a modifier in the bitumen binder. Therefore, this study aimed to provide a solution to such a significant environmental problem. Five different ratios of waste mask and the single ratio of styrene-butadienestyrene (SBS) were added to the pure binder and the rheological, physical, and chemical properties of the modified binders were compared. The result showed that adding a waste mask and SBS to the pure bitumen caused increases in binders' softening point and viscosity and reductions in the penetration value. Waste mask modifications were able to better maintain its elastic properties both at low stress and high-stress levels with increasing temperature. 3% SBS was the binder most affected by temperature rise. As a result, it has been determined that binders containing more than 2% waste mask have better performance characteristics than binders containing 3% SBS in terms of physical and rheological properties.

After the coronavirus outbreak, a tremendous amount of personal protective equipment has been produced and used by the health service and every human. Proper medical waste management becomes an important problem, which must be solved with a minimal environmental impact. The presented manuscript introduces the recycling process, during which personal protection masks are transformed into polypropylene fibers being an addition to a concrete mixture. The designed recycling procedure provides the entire disinfection of probably contaminated medical wastes, is straightforward, and potentially enables one to modify the properties of the final product. The applied dosage referred to 1 mask per 1 L of concrete. The final product of face masks processing was studied using Fourier-transform infrared spectroscopy, thermogravimetric analysis, surface free energy, contact angle measurements, and melt flow index. The analysis indicated that polypropylene is its main component. Two concrete mixtures were composed, i.e., with the addition of processed masks and the reference one. The following properties were determined to compare the modified concrete with the reference one: compressive and tensile strength, frost resistance, water transport properties, resistance to high temperature. The obtained results indicated that the addition of processed masks slightly increased the compressive strength (by about 5%) and decreased the tensile strength (by about 3%). Simultaneously, it was reported that the addition did not affect material properties related to concrete durability as frost resistance, water permeability, and fire performance. The results evinced, that the addition of processed facemasks into concrete did not deteriorate its properties. Therefore, it is a possible way of the protective masks processing and reusing with the high recycling capacity. Further study should be conducted to optimize the dosing and to modify the properties of PP strings to improve hardened concrete properties.

This paper presents the results of long-term experiments performed on three timber-concrete composite (TCC) beams. An innovative fabricated steel plate connection system, which consists of screws and steel plates embedded in concrete slabs, was adopted in the TCC beam specimens. The adopted shear connection can provide dry-type connection for TCC beams. Steel plates were embedded in concrete slabs while the concrete slab was constructed in factories. The timber beam and concrete slab can be assembled together using screws at the construction site. In this experimental programme, the beam specimens were subjected to constant loading for 613 days in indoor uncontrolled environments. The influence of long-term loading levels and the number of shear connections on the long-term performance of TCC beams was investigated and discussed. The mid-span deflection, timber strain, and interface relative slip at the positions of both connections and beam-ends were recorded throughout the long-term tests. It was found the long-term deflection of the TCC beam increased by approximately 60% while the long-term loads were doubled. Under the influence of the variable temperature and humidity, the TCC specimens with 8 shear connections showed slighter fluctuations compared with the TCC beam with 6 shear connections. In the 613-day observation period, the maximum deflection increment recorded was 6.56 mm for the specimen with eight shear connections and 20% loading level. A rheological model consisting of two Kelvin bodies was employed to fit the curves of creep coefficients. The final deflections predicted of all specimens at the end of 50-year service life were 2.1~2.7 times the initial deflections caused by the applied loads. All beam specimens showed relative small increments in mid-span deflection, strain and relative slip over time without any degradations, demonstrating the excellent long-term performance of TCC beams using the innovative steel plate connection system, which is also easily fabricated.

Silica fume (SF) as an important supplementary cementitious material has been widely used in Portland cement, but few published articles have reported on the effect of SF on the performance and hydration mechanism of basic magnesium sulfate cement (BMSC). In the present work, the properties, microstructure and hydration mechanism of BMSC influenced by SF was studied systematically. The results show that the setting time and compressive strength of BMSC may increase with the increase of SF content, while the hydration heat will decrease with the increase of SF content. Mercury intrusion porosimetry (MIP), X-ray computed tomography (X-CT), scanning electron microscope- Energy dispersive spectrometer (SEM-EDS) results show that SF exhibits filling effect in the BMSC matrix, which makes the microstructure of BMSC matrix with SF more compact. In addition, solid-state magnetic resonance (NMR) and SEM-EDS analysis indicate that the activity of SF was excited in the BMSC matrix, resulting in the formation of M-S-H gel.

Concrete structures in sewer systems, marine engineering, underground engineering and other humid environments are easily subjected to microbial attachment, colonization and, eventually, deterioration. With careful selection and treatment, some additives including inorganic and organic antimicrobial agents were found to be able to endow concrete with excellent antimicrobial performance. This paper reviews various types of antimicrobial concrete fabricated with different types of antimicrobial agents. The classification and methods of applying antimicrobial agents into concrete are briefly introduced. The antimicrobial and mechanical properties as well as mass/weight loss of concrete incorporating antimicrobial agents are summarized. Applications reported in this field are presented and future research opportunities and challenges of antimicrobial concrete are also discussed in this review.

Bond between two cementitious materials is crucial in applications such as repairs, overlays, and connections of prefabricated bridge elements (PBEs), to name just a few. It is the latter that has special interest to the authors of this paper. After performing a dimensional stability study on grout-like materials commonly used as connections between PBEs, it was observed that the so-called 'non-shrink' cementitious grouts showed a considerable amount of early-age shrinkage. This might have negative effects on the integrity of the structure, due not only to the grout material's early degradation, but also to a possible loss of bond between the grout and the prefabricated concrete element. Many factors affect the bond strength between two cementitious materials (e.g., grout-concrete), the presence of moisture at the existing concrete substrate surface being one of them. In this regard, pre-moistening the concrete substrate surface prior to the application of the grout material is sometimes recommended for bond enhancement. This topic has been the focus of numerous research studies in the past; however, there is still controversy among practitioners on the real benefits that this practice might provide. This paper evaluates the tensile bond performance of two non-shrink cementitious grouts applied to the exposed aggregate surface of a concrete substrate, and how the supply of moisture at the grout-concrete interface affects the bond strength. "Pull-off" bond results show increased tensile bond strength when the concrete surface is pre-moistened. Reasons to explain the observed increased bond strength are given after a careful microstructural analysis of the grout-concrete interface. Interfaces where sufficient moisture is provided to the concrete substrate such that moisture movement from the grout is prevented show reduced porosity and increased hydration on the grout side of the interface, which is thought to directly contribute to the increased tensile bond strength.

Fly ash is frequently used as a replacement for cement in concrete. However, questions remain regarding the influence that fly ash has on the hydration of cement. This paper examines physical aspects (e.g., surface nucleation, cement particle spacing) and chemical aspects (e.g., pozzolanic and hydraulic reactions) of the fly ash and cement in mixtures containing high volumes of fly ash. In addition to using fly ash, a chemically inert filler was used consisting of a blend of fine silica sands with approximately the same particle size distribution as that of the fly ash. The paper compares reactivity results from 1) cement, 2) cement-fly ash and 3) cement-inert filler systems. Isothermal calorimetry measurements are used to quantitively evaluate the role played by the fly ash in hydration of high volume fly ash mixtures. The results provide a decoupling of the physical and chemical effects of high volume fly ash on cement hydration.

The viscoelastic/viscoplastic behavior of cement paste may occur due to intrinsic calcium silicate hydrate (C-S-H) viscoelasticity/viscoplasticity and cement grain dissolution during the hydration process. A numerical model that combines a microstructure model and a finite element calculation model has been developed to predict the time-dependent behavior of cementitious materials based on these two mechanisms, while incorporating C-S-H intrinsic aging. The simulation results from the model suggest that when considering C-S-H aging, the time-dependent properties of C-S-H are capable of generating the aging effect of cement paste, and can become a significant mechanism leading to the overall relaxation of cement paste.

During steam curing of concrete, temperature and moisture gradients are developed, which are difficult to measure experimentally and can adversely affect the durability of concrete. In this research, a model of cement hydration coupled to moisture and heat transport was used to simulate the process of steam curing of mortars with water-to-cement () ratios by mass of 0.30 and 0.45, considering natural convection boundary conditions in mortar and concrete specimens of AASHTO Type VI beams. The primary variables of the model were moisture content, temperature, and degree of hydration. Moisture content profiles of mortar specimens (40 mm in diameter and 50 mm in height) were measured by magnetic resonance imaging. The degree of hydration was obtained by mass-based measurements of loss on ignition to 1000 °C. The results indicate that the model correctly simulates the moisture distribution and degree of hydration in mortar specimens. Application of the model to the steam curing of an AASHTO Type VI beam indicates temperature differences (between the surface and the center) higher than 20 °C during the cooling stage, and internal temperatures higher than 70 °C that may compromise the durability of the concrete.

A microstructure model has been applied to simulate near-surface degradation of portland cement paste in contact with a sodium sulfate solution. This new model uses thermodynamic equilibrium calculations to guide both compositional and microstructure changes. It predicts localized deformation and the onset of damage by coupling the confined growth of new solids with linear thermoelastic finite element calculations of stress and strain fields. Constrained ettringite growth happens primarily at the expense of calcium monosulfoaluminate, carboaluminate and aluminum-rich hydrotalcite, if any, respectively. Expansion and damage can be mitigated chemically by increasing carbonate and magnesium concentrations or microstructurally by inducing a finer dispersion of monosulfate.