High concentrations of protein wastewater often reduce treatment efficiency due to ammonia inhibition and acid accumulation caused by its low carbon-to-nitrogen ratio (C/N) after digestion, as well as its complex structure. This study investigates the performance of a microbial electrolysis cell (MEC) driving a protein digestion system with gradually increasing organic loading rates (OLR) of bovine serum albumin, elucidating microbial changes and methanogenic metabolic pathways on bioelectrodes under high OLR "inhibited steady-state" (ISS) conditions. The results showed that the accumulation of ammonia nitrogen (AN) from protein hydrolysis under high OLR conditions disrupted microbial growth and caused cell death on the electrode surface, hindering the electron transfer rate. Toxic AN reduced protein hydrolysis, led to propionate accumulation, inhibiting the acetoclastic methanogenesis process and favoring the hydrogenotrophic pathway. As OLR increased from 6 to 11 gCOD/L, cumulative methane production increased significantly from 450.24 mL to 738.72 mL, while average methane yield and production rate decreased by 10.51% and 50.28%, from 375.20 mL/gCOD and 75.04 mL/(gCOD·d) to 335.78 mL/gCOD and 37.31 mL/(gCOD·d), respectively. Despite these declines, the system maintained an ISS. Moderate OLR increases can achieve an ISS, boosting protein waste treatment capacity, methane production, and net energy output (NEO), with an OLR of 6 gCOD/L being optimal for maximizing NEO per unit substrate. These findings provide theoretical insights into the methanogenesis pathway of high OLR proteins in MEC-AD systems and offer an effective method for treating high OLR protein wastewater in future practical applications.

In response to the COVID-19 pandemic, some vaccines have been developed requiring ultralow-temperature refrigeration, and the number of these freezers has been increased worldwide. Ultralow-temperature refrigeration operates with a significant temperature lift and, hence, a massive decrease in energy performance. Therefore, cascade cycles based on two vapor compression single-stage cycles are traditionally used for these temperatures. This paper proposes the combination of six different cycles (single-stage with and without internal heat exchanger, vapor injection, liquid injection, and parallel compression with and without economizer) in two-stage cascades to analyze the operational and energy performance in ultralow-temperature freezers. All this leads to 42 different configurations in which the intermediate cascade temperature is optimized to maximize the coefficient of performance. Ultra-low global warming potential natural refrigerants such as R-290 (propane) and R-170 (ethane) for the cascade high- and low-temperature stage have been considered. From the thermodynamic analysis, it can be concluded that liquid and vapor injection cascade configurations are the most energy-efficient. More specifically, those containing a vapor injection in the low-temperature stage (0.89 coefficient of performance, 40 % higher than traditional configurations). Then, using an internal heat exchanger for such low temperatures is unnecessary in terms of energy performance. The optimum intermediate cascade temperature varies significantly among cycles, from -37 °C to 2 °C, substantially impacting energy performance. Parallel compression configuration improves energy performance over single-stage cycles, but not as much as multi-stage (between 20 % and 30 % lower coefficient of performance). For most of low-temperature cycles, the high-temperature stage can be based on a single-stage cycle while keeping the maximum coefficient of performance.

CO-based ground-source heat pumps (GSHPs) have the potential to be very environmentally friendly, since GSHPs operate with high energy efficiency, and CO has no ozone depletion potential (ODP) and a low global warming potential (GWP). We developed a prototype CO liquid-to-air GSHP to investigate its performance potential in residential applications. Further, we developed a detailed model of the system that simulates both cooling and heating operation; the model is the primary focus of this report. The model simulates both subcritical and transcritical operation since the system regularly operates near and above the critical temperature of CO (30.98 °C) during heating and cooling operation. The model considered both the refrigerant-side thermodynamic and transport processes in the cycle, as well as the air-side heat transfer and moisture removal. We performed cooling tests for the prototype CO GSHP that included those from the International Standards Organization (ISO) 13256-1 standard for liquid-to-air heat pumps, as well as extended tests at additional entering liquid temperatures (ELTs). The model predicted the measurements within 0.5 % to 6.7 % for COP, 1.0 % to 3.6 % for total capacity, and 3.3 % to 4.9 % for sensible capacity. We compared the measured cooling performance to published performance data for a commercially-available R410A GSHP and found that for ELTs below 20 °C, the CO GSHP has a higher cooling COP and total capacity than the R410A GSHP. At the 'standard' cooling rating condition (ELT 25 °C), the CO GSHP COP was 4.14 and the R410A GSHP COP was 4.43. At 'part-load' conditions (ELT 20 °C) the CO GSHP COP was 4.92 and the R410A GSHP COP was 4.99. In the future, the model can be used to investigate methods to improve the CO GSHP performance to meet or exceed that of the R410A system over a wider range of ELTs; possible studies include replacing the electronic expansion valve (EEV) with an ejector, optimizing the charge, and optimizing the heat exchanger geometry and circuiting.

In this study, stack design for high concentration gradient reverse electrodialysis operating in recycle is addressed. High concentration gradients introduce complex transport phenomena, which are exacerbated when recycling feeds; a strategy employed to improve system level energy efficiency. This unique challenge indicates that membrane properties and spacer thickness requirements may differ considerably from reverse electrodialysis for lower concentration gradients (e.g. seawater/river water), drawing closer parallels to electrodialysis stack design. Consequently, commercially available electrodialysis and reverse electrodialysis stack design was first compared for power generation from high concentration gradients. Higher gross power densities were identified for the reverse electrodialysis stack, due to the use of thinner membranes characterised by a higher permselectivity, which improved current. However, energy efficiency of the electrodialysis stack was twice that recorded for the reverse electrodialysis stack at low current densities, which was attributed to: (i) an increased residence time provided by the larger intermembrane distance, and (ii) reduced exergy losses of the electrodialysis membranes, which provided comparatively lower water permeance. Further in-depth investigation into membrane properties and spacer thickness identified that membranes characterised by an intermediate water permeability and ohmic resistance provided the highest power density and energy efficiency (Neosepta ACS/CMS), while wider intermembrane distances up to 0.3 mm improved energy efficiency. This study confirms that reverse electrodialysis stacks for high concentration gradients in recycle therefore demand design more comparable to electrodialysis stacks to drive energy efficiency, but when selecting membrane properties, the trade-off with permselectivity must also be considered to ensure economic viability.

A detailed thermochemical analysis is carried out to assess the energetic performance of a proposed process based on liquid metal slurry in a chemical looping gasification process. The system is designed to produce synthetic gas and generate electricity from low-grade (waste) solid carbon black collected from a thermal plasma plant. Indium oxide-indium slurry mixture was used as an oxygen carrier. The thermodynamic models showed that oxygen availability in the fuel reactor is the determining parameter that controls the operating mode of the system. The molar ratio of liquid metal to feedstock (LMO/C) and the steam to feedstock (S/C) are identified the key factors that regulate the level of exergy partitioned in the gas products. Generating steam by heat-recovery from the vitiated air (exhausted from the air reactor), is a proof that the process is partially self-sustained - capable of generating electricity to drive the pumps and the air compressors in the process. At LMO/C = 0.1 and S/C = 1.5, the largest exergy is partitioned in the synthetic gas and a syngas quality (molar ratio of H: CO) of ~1.55 is achieved. The highest syngas quality was achievable, however, at the cost of unreacted steam, which increased the exergy destruction of the plant. The peak performance of the system is achieved when the (fuel and air) reactors operated at near-isothermal conditions. At these conditions, the exergy destruction between reactors is minimised and the power production in the power block is maximised. Based on indicative available price indexes, a techno-economic analysis evaluated the economic viability and the levelised cost of energy for a different price for various scenarios. It showed that the proposed system offers a competitive LCOE against several existing energy and hydrogen production systems.

Road transport is one of the main sources of greenhouse gas emissions due to the current dependence on fossil fuels such as diesel and gasoline. This situation needs to be changed through the retirement of fossil fuels and the implementation of alternative fuels and vehicles such as biofuels, battery electric vehicles, and fuel cell electric vehicles fuelled by hydrogen. Nevertheless, the environmental suitability of alternative fuels is conditioned by how they are produced. Through the case study of Spain, this article prospectively assesses - from a techno-economic and carbon footprint perspective- the production technology mix of alternative fuels from 2020 to 2050. The proposed energy systems optimisation model includes a large number of production technologies regarding biofuels (bioethanol, biodiesel, synthetic diesel/gasoline, and hydrotreated vegetable oil), electricity, and hydrogen. The combined study of these fuels provides a relevant framework to discuss the targets established for the road transport sector with a high level of detail not only regarding fuel type but also technology breakdown. The results show the relevance of second-generation biofuel production technologies in fulfilling the future biofuel demand. Regarding the extra electricity demand associated with the penetration of electric vehicles, the results suggest a key role of wind- and solar-based technologies in meeting such a need. Concerning hydrogen as an option to decarbonise the transport system, even though steam methane reforming is the most mature and cost-competitive production technology, hydrogen production would be satisfied through electrolysis in order to avoid relying on fossil resources as the main feedstock. Overall, this integrated approach to the long-term production technology mix of alternative fuels for road transport is expected to be relevant to a wide range of decision-makers willing to prospectively assess road transport systems from a technology perspective.

Thermoeconomic analysis, a combined application of thermodynamic and economic analyses, has emerged as an important tool to optimize the performance of desalination systems. Contrary to conventional economic analysis, it offers flexibility to investigate and improve the performance of each component in the system, individually. The current paper presents a comprehensive framework for conducting thermoeconomic analysis of desalination systems. In this regard, different energy calculation methods are discussed first. Then a detailed review of theoretical developments of thermoeconomic analyses is conducted to summarize the correlations/magnitude of important economic parameters. This is followed by a discussion on cost balance equations for important desalination components. Finally, a systematic thermoeconomic analysis model is developed for the mechanical vapor compression desalination system operating under different arrangements as an example. The monetary value of each stream calculated using appropriate fiscal parameters in the system is presented in the form of a cost flow diagram. The study can be used to conduct the thermoeconomic analysis of other commercial desalination systems.

One of the strategies to reduce the environmental impacts associated with electricity is to employ renewable resources such as biomass or even waste. However, the evaluation of the sustainability of a power plant depends on the development of several analyses, which should encompass thermodynamic and environmental parameters. Energy, exergy, and exergoenvironmental assessments are carried out for a sugarcane bagasse cogeneration system, along with a Life Cycle Assessment for the Brazilian sugarcane bagasse, employing the Eco-indicator 99 method. The specific environmental impacts of electricity and steam are 6.023 mPt/MJ and 4.038 mPt/MJ, respectively, and the boiler feed pump and radiator presented the highest average environmental impact per exergy of fuel and product, respectively. The component with the highest exergoenvironmental factor was the furnace (60.32%), demonstrating margins for benefits in the formation of pollutants and destruction of exergy. Exergoenvironmental assessments can be utilized to support the adoption of more efficient (although more complex) cogeneration systems, especially in the aftermath of the COVID-19 crisis.

Off-grid electrification of remote communities using sustainable energy systems (SESs) is a requisite for realizing sustainable development goals. Nonetheless, the capacity planning of the SESs is challenging as it needs to fulfil the fluctuating demand from a long-term perspective, in addition to the intermittency and unpredictable nature of renewable energy sources (RESs). Owing to the nonlinear and non-convex nature of the capacity planning problem, an efficient technique must be employed to achieve a cost-effective system. Existing techniques are, subject to some constraints on the derivability and continuity of the objective function, prone to premature convergence, computationally demanding, follows rigorous procedures to fine-tune the algorithm parameters in different applications, and often do not offer a fair balance during the exploitation and exploration phase of the optimization process. Furthermore, the literature review indicates that researchers often do not implement and examine the energy management scheme (EMS) of a microgrid while computing for the capacity planning problem of microgrids. This paper proposes a rule-based EMS (REMS) optimized by a nature-inspired grasshopper optimization algorithm (GOA) for long-term capacity planning of a grid-independent microgrid incorporating a wind turbine, a photovoltaic, a battery (BT) bank and a diesel generator ( ). In which, a rule-based algorithm is used to implement an EMS to prioritize the usage of RES and coordinate the power flow of the proposed microgrid components. Subsequently, an attempt is made to explore and confirm the efficiency of the proposed REMS incorporated with GOA. The ultimate goal of the objective function is to minimize the cost of energy (COE) and the deficiency of power supply probability (DPSP). The performance of the REMS is examined via a long-term simulation study to ascertain the REMS resiliency and to ensure the operating limit of the BT storage is not violated. The result of the GOA is compared with particle swarm optimization (PSO) and a cuckoo search algorithm (CSA). The simulation results indicate that the proposed technique's superiority is confirmed in terms of convergence to the optimal solution. The simulation results confirm that the proposed REMS has contributed to better adoption of a cleaner energy production system, as the scheme significantly reduces fuel consumption, emission and COE by 92.4%, 92.3% and 79.8%, respectively as compared to the conventional . The comparative evaluation of the algorithms shows that REMS-GOA yields a better result as it offers the least COE (objective function), at $0.3656/kW h, as compared to the REMS-CSA at $0.3662/kW h and REMS-PSO at $0.3674/kW h, for the desired DPSP of 0%. Finally, sensitivity analysis is performed to highlight the effect of uncertainties on the system inputs that may arise in the future.

In this work, we investigated the impact of temperature on two-phase transport in low temperature (LT)-polymer electrolyte membrane (PEM) electrolyzer anode flow channels via neutron imaging and observed a decrease in mass transport overpotential with increasing temperature. We observed an increase in anode oxygen gas content with increasing temperature, which was counter-intu.itive to the trends in mass transport overpotential. We attributed this counterintuitive decrease in mass transport overpotential to the enhanced reactant distribution in the flow channels as a result of the temperature increase, determined via a one-dimensional analytical model. We further determined that gas accumulation and fluid property changes are competing, temperature-dependent contributors to mass transport overpotential; however, liquid water viscosity changes led to the dominate enhancement of reactant water distributions in the anode. We present this temperature-dependent mass transport overpotential as a great opportunity for further increasing the voltage efficiency of PEM electrolyzers.

The demand for better hygiene has increased the need for developing more effective sanitation systems and facilities for the safe disposal of human urine and faeces. Non-Sewered Sanitary systems are considered to be one of the promising alternative solutions to the existing flush toilet system. An example of these systems is the Nano Membrane Toilet (NMT) system being developed at Cranfield University, which targets the safe disposal of human waste while generating power and recovering water. The NMT will generate energy from the conversion of human waste with the use of a micro-combustor; the heat produced will power a Stirling engine connected to a linear alternator to generate electricity. This study presents a numerical investigation of the thermodynamic analysis and operational characteristics of a quasi steady state model of the gamma type Stirling engine integrated into a combustor in the back end of the NMT system. The effects of the working gas, at different temperatures, on the Stirling engine performance are also presented. The results show that with the heater temperature of 390 °C from the heat supply via conduction at 820 W from the flue gas, the Stirling engine generates a daily power output of 27 Wh/h at a frequency of 23.85 Hz.

A probabilistic modelling approach was developed and applied to investigate the energy and environmental performance of an innovative sanitation system, the "Nano-membrane Toilet" (NMT). The system treats human excreta via an advanced energy and water recovery island with the aim of addressing current and future sanitation demands. Due to the complex design and inherent characteristics of the system's input material, there are a number of stochastic variables which may significantly affect the system's performance. The non-intrusive probabilistic approach adopted in this study combines a finite number of deterministic thermodynamic process simulations with an artificial neural network (ANN) approximation model and Monte Carlo simulations (MCS) to assess the effect of system uncertainties on the predicted performance of the NMT system. The joint probability distributions of the process performance indicators suggest a Stirling Engine (SE) power output in the range of 61.5-73 W with a high confidence interval (CI) of 95%. In addition, there is high probability (with 95% CI) that the NMT system can achieve positive net power output between 15.8 and 35 W. A sensitivity study reveals the system power performance is mostly affected by SE heater temperature. Investigation into the environmental performance of the NMT design, including water recovery and CO/NO emissions, suggests significant environmental benefits compared to conventional systems. Results of the probabilistic analysis can better inform future improvements on the system design and operational strategy and this probabilistic assessment framework can also be applied to similar complex engineering systems.

This article describes the design and commissioning of a micro-combustor for energy recovery from human faeces, which can operate both in updraft and downdraft modes. Energy recovery from faecal matter via thermochemical conversion has recently been identified as a feasible solution for sanitation problems in low income countries and locations of high income countries where access to sewage infrastructures is difficult or not possible. This technology can be applied to waterless toilets with the additional outcome of generating heat and power that can be used to pre-treat the faeces before their combustion and to ensure that the entire system is self-sustaining. The work presented here is framed within the Nano Membrane Toilet (NMT) project that is being carried out at Cranfield University, as part of the Reinvent the Toilet Challenge of the Bill and Melinda Gates Foundation. For this study, preliminary trials using simulant faeces pellets were first carried out to find out the optimum values for the main operating variables at the scale required by the process, i.e. a fuel flowrate between 0.4 and 1.2 g/min of dry faeces. Parameters such as ignition temperature, residence time, and maximum temperature reached, were determined and used for the final design of the bench-scale combustor prototype. The prototype was successfully commissioned and the first experimental results, using real human faeces, are discussed in the paper.

In this study, human feces were hydrothermal liquefied and converted into biocrude over Ni-Tm/TiO catalyst. The influence of catalysts, reaction temperature, and holding time on the distribution of products and element content of biocrude was assessed. The biocrude yield increased to 53.16% with a reaction temperature of 330 °C, a holding time of 30 min, and adding Ni-Tm/TiO catalyst while the liquefaction conversion peaked at 89.61%. The biocrude had an HHV of 36.64 MJ/kg and was similar to heavy crude oil. The biocrude is rich in fatty acid amides, esters, and oxygen-containing-only heteroatom-ring compounds as well as some nitrogen-containing heteroatom-ring compounds. The main gaseous products were CO, CH, and CH. Hydrothermal liquefaction over Ni-Tm/TiO catalyst could be a potential method to handle human excrement treatment and produce biofuel.

With about 2.4 billion people worldwide without access to improved sanitation facilities, there is a strong incentive for development of novel sanitation systems to improve the quality of life and reduce mortality. The Nano Membrane Toilet is expected to provide a unique household-scale system that would produce electricity and recover water from human excrement and urine. This study was undertaken to evaluate the performance of the conceptual energy and water recovery system for the Nano Membrane Toilet designed for a household of ten people and to assess its self-sustainability. A process model of the entire system, including the thermochemical conversion island, a Stirling engine and a water recovery system was developed in Aspen Plus®. The energy and water recovery system for the Nano Membrane Toilet was characterised with the specific net power output of 23.1 Wh/kg and water recovery rate of 13.4 dm/day in the nominal operating mode. Additionally, if no supernatant was processed, the specific net power output was increased to 69.2 Wh/kg. Such household-scale system would deliver the net power output (1.9-5.8 W). This was found to be enough to charge mobile phones or power clock radios, or provide light for the household using low-voltage LED bulbs.

Non-sewered sanitary systems (NSS) are emerging as one of the solutions to poor sanitation because of the limitations of the conventional flush toilet. These new sanitary systems are expected to safely treat faecal waste and operate without external connections to a sewer, water supply or energy source. The Nano Membrane Toilet (NMT) is a unique domestic-scale sanitary solution currently being developed to treat human waste on-site. This toilet will employ a small-scale gasifier to convert human faeces into products of high energy value. This study investigated the suitability of human faeces as a feedstock for gasification. It quantified the recoverable exergy potential from human faeces and explored the optimal routes for thermal conversion, using a thermodynamic equilibrium model. Fresh human faeces were found to have approximately 70-82 wt.% moisture and 3-6 wt.% ash. Product gas resulting from a typical dry human faeces (0 wt.% moisture) had LHV and exergy values of 17.2 MJ/kg and 24 MJ/kg respectively at optimum equivalence ratio of 0.31, values that are comparable to wood biomass. For suitable conversion of moist faecal samples, near combustion operating conditions are required, if an external energy source is not supplied. This is however at 5% loss in the exergy value of the gas, provided both thermal heat and energy of the gas are recovered. This study shows that the maximum recoverable exergy potential from an average adult moist human faeces can be up to 15 MJ/kg, when the gasifier is operated at optimum equivalence ratio of 0.57, excluding heat losses, distribution or other losses that result from operational activities.

This study compared the energy performance and initial cost of photovoltaic (PV) and heating, ventilating, and air-conditioning (HVAC) equipment for a residential net-zero energy building (NZEB) in different climate zones across the United States. We used an experimentally validated building simulation model to evaluate various electrically-powered and commercially-available HVAC technologies. The HVAC accounted for 23.8 % to 72.9 % of the total building energy depending on the HVAC option and climate zone. Each HVAC configuration was paired with a PV system sized to exactly reach the net-zero energy target, so the economics were compared based on the initial PV + HVAC cost. Mechanical ventilation was considered with and without heat recovery; the heat recovery ventilator (HRV) saved a significant amount of energy in cold winter months and hot summer months, and the energy recovery ventilator (ERV) provided additional benefit for humid zones. The HRV was cost-effective in the cold northern latitudes of Chicago, Minneapolis, Helena, and Duluth, where energy savings reached 17.3 % to 19.7 %. In other climates, ventilation without recovery was more cost effective, by 1 % to 9 %, and sometimes even more energy efficient. The ERV was never the lowest cost option. A ground-source heat pump (GSHP) and an air-source heat pump (ASHP) were compared, with the GSHP providing significant energy savings, 24.3 % to 39.2 %, in heating-dominated climates (Chicago through Duluth). In warmer climates, the GSHP saved little energy or used more energy than the ASHP. The PV + HVAC cost was lower everywhere with the ASHP, though it is possible for colder climates that a carefully sized GSHP and ground loop could be cost-competitive. The energy and cost data as well as the required PV capacity could guide HVAC and PV designs for residential NZEBs in different climate zones.